Chelsea registered 34 attempts during the contest, their largest tally in a WSL fixture since the beginning of last season.
James made an immediate impact, firing an excellent effort into the top of the net after only 11 minutes, leaving Chelsea supporters anticipating many more goals.
Villa offered almost no attacking threat and managed just five touches inside the Chelsea penalty area.
However, despite the balance of play, Noelle Maritz’s late effort deflected off goalkeeper Hannah Hampton before rebounding into the net from Chelsea defender Veerle Buurman.
Villa manager Natalia Arroyo celebrated with her arms raised as the visiting fans broke the stunned silence around Stamford Bridge.
Bompastor said the performance and match statistics made the failure to win difficult to understand, particularly because her side created so many chances.
She explained that scoring two or three goals would have effectively settled the contest and produced a very different second half.
The manager added that Chelsea must play faster, maintain their intensity and push harder to finish games off, something they failed to do on this occasion.
She admitted that everyone was frustrated because the final result was disappointing.
A major source of Bompastor’s frustration was her limited ability to change the situation.
Summer arrival Melvine Malard was unavailable after sustaining a minor training injury, while Mayra Ramirez remained in recovery, leaving Chelsea short of attacking alternatives.
England striker Aggie Beever-Jones started up front following Sam Kerr’s recent departure, but she appeared to be struggling for confidence.
She failed to convert several openings, and when she finally found the net, the goal was disallowed for offside.
Bompastor said the team must respond by remaining confident, staying united and continuing to work hard.
She noted that such difficulties can be psychological, emphasizing the need for a more decisive and clinical mentality inside the penalty area.
According to the manager, elite teams often require only one or two opportunities to secure victory, and Chelsea must improve in that area.
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